Finch was married three times. In 1943, he married Romanian-born French ballerina Tamara Tchinarova; they worked together on a number of films. They had a daughter, Anita, born in 1950. They divorced in 1959, after she discovered his affair with actress Vivien Leigh in California. He then married South African-born actress Yolande Turner (née Yolande Eileen Turnbull); they had two children together, Samantha and Charles Peter. During their marriage, Finch had an affair with the singer Shirley Bassey. Bassey had a daughter, also named Samantha, born in 1963; Bassey's husband at the time, the openly gay film producer Kenneth Hume, believed that Finch was her biological father. Finch and Turner divorced in 1965. In 1972 Finch married Mavis "Eletha" Barrett, who was known as Eletha Finch. They had a daughter together, Diana.
He did radio acting work with Hugh Denison's BSA Players (for Broadcasting Service Association, later to become Macquarie Players). He came to the attention of Australian Broadcasting Commission radio drama producer Lawrence H. Cecil, who was to act as his coach and mentor throughout 1939 and 1940. He was "Chris" in the Children's Session and the first Muddle-Headed Wombat.
Finch returned to Australia to make The Shiralee (1957), one of his favourite parts, and the tenth most popular movie at the British box office that year. He followed it with another Australian story, the bushranger tale Robbery Under Arms (1957), which did less well. However exhibitors still voted Finch the third most popular British star of 1957, and the fifth most popular overall, regardless of nationality.
Finch's film roles increased in size and prestige through the early 1950s. For Walt Disney he played the Sheriff of Nottingham in The Story of Robin Hood and His Merrie Men (1952). He was given two good roles in films from Alexander Korda: as Richard D'Oyly Carte in The Story of Gilbert and Sullivan (1953), and as a priest in The Heart of the Matter (1953), from the Graham Greene novel.
He was soon cast in his first British movie, playing a murderous actor in Train of Events (1949). Critic C. A. Lejeune praised his work in the London Observer commenting that he "adds good cheekbones to a quick intelligence and is likely to become a cult, I fear." The Scotsman said "he should be regarded as one of the most hopeful recruits to the British screen."
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